Botrylactone: new interest in an old moleculedreview of its absolute configuration and related compounds

Identificadores
URI: http://hdl.handle.net/10498/17363
DOI: 10.1016/j.tet.2010.11.022
ISSN: 0040-4020
Statistics
Metrics and citations
Share
Metadata
Show full item recordDate
2010-11-11Department
Química OrgánicaSource
Tetrahedron, 2011, vol. 67, pp. 417-420Abstract
The absolute configuration of botrylactone, a unique compound with an interesting polyketide lactone
skeleton with two oxirane bridges previously isolated from Botrytis cinerea and described as a powerful
antibiotic, has been reviewed on the basis of sign of the optical rotation, NOE experiments and NMR
method. The isolation of 7-deoxybotrylactone and 5-hydroxy-7-(4-hydroxydec-2(3)-enoyl) botrylactone
enables us to characterize an intriguing new family of compounds with this interesting polyketide
skeleton. A common biosynthetic origin with botcinin derivatives is proposed.
Subjects
Botrylactone; Absolute configurationCollections
- Artículos Científicos [4821]
- Artículos Científicos INBIO [264]
- Artículos Científicos INIBICA [491]
- Artículos Científicos IVAGRO [289]
- Articulos Científicos Quim. Org. [174]