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Allylic Oxidation of Alkenes Catalyzed by a Copper−Aluminum Mixed Oxide

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URI: http://hdl.handle.net/10498/20368

DOI: 10.1021/ol500198c

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2014-Allylic oxidation of alkenes catalyzed by a copper-aluminum mixed oxide.pdf (924.0Kb)
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Author/s
García-Cabeza, Ana Leticia; Marín Barrios, Rubén; Moreno Dorado, Francisco JavierAuthority UCA; Guerra, Francisco M.; Ortega Agüera, María JesúsAuthority UCA; Martínez Massanet, Guillermo
Date
2014-03
Department
Química Orgánica
Source
Organic Letters 2014, 16, 1598−1601
Abstract
A strategy for the allylic oxidation of cyclic alkenes with a copper−aluminum mixed oxide as catalyst is presented. The reaction involves the treatment of an alkene with a carboxylic acid employing tert-butyl hydroperoxide as the oxidant. In all cases, the corresponding allylic esters are obtained. When L-proline is employed, the allylic alcohol or ketone is obtained. The oxidation of cyclohexene and valencene has been optimized by design of experiments (DoE) statistical methodology.
Subjects
allylic oxidation
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  • Artículos Científicos [4980]
  • Artículos Científicos INBIO [269]
  • Articulos Científicos Quim. Org. [180]
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
This work is under a Creative Commons License Attribution-NonCommercial-NoDerivatives 4.0 Internacional

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