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Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B$NH3 as probed by experiment and computation

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URI: http://hdl.handle.net/10498/21336

DOI: 10.1039/c4sc00735b

ISSN: 2041-6520

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2014-Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computation.pdf (932.3Kb)
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Author/s
Kumar, Amit; C. Johnson, Heather; N. Hooper, Thomas; S. Weller, Andrew; García Algarra, AndrésAuthority UCA; A. Macgregor, Stuart
Date
2014
Department
Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
Source
Chem. Sci., 2014, 5, 2546–2553
Abstract
Multiple metal-bound oligomers in the dehydropolymerisation of H3B$NH3 have been observed by electrospray-ionisation mass spectrometry and NMR spectroscopy using the catalytic metal fragment {Ir(PCy3)2(H)2}+. A computational study suggests that sterics dictate whether multiple dehydrogenation/ B–N coupling of amine-boranes H3B$NRR'H (R, R0 ¼ Me or H) is observed, and also demonstrates the experimentally observed requirement for additional amine-borane to promote dehydrocoupling.
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Attribution-NonCommercial-NoDerivatives 4.0 Internacional
This work is under a Creative Commons License Attribution-NonCommercial-NoDerivatives 4.0 Internacional

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