@misc{10498/17363, year = {2010}, month = {11}, url = {http://hdl.handle.net/10498/17363}, abstract = {The absolute configuration of botrylactone, a unique compound with an interesting polyketide lactone skeleton with two oxirane bridges previously isolated from Botrytis cinerea and described as a powerful antibiotic, has been reviewed on the basis of sign of the optical rotation, NOE experiments and NMR method. The isolation of 7-deoxybotrylactone and 5-hydroxy-7-(4-hydroxydec-2(3)-enoyl) botrylactone enables us to characterize an intriguing new family of compounds with this interesting polyketide skeleton. A common biosynthetic origin with botcinin derivatives is proposed.}, publisher = {Elsevier}, keywords = {Botrylactone}, keywords = {Absolute configuration}, title = {Botrylactone: new interest in an old moleculedreview of its absolute configuration and related compounds}, doi = {10.1016/j.tet.2010.11.022}, author = {Pinedo Rivilla, Cristina and Moraga Galindo, Javier and Hernández Galán, Rosario and Durán Patrón, Rosa María and González Collado, Isidro}, }