@misc{10498/20323, year = {2015}, month = {12}, url = {http://hdl.handle.net/10498/20323}, abstract = {A phytochemical study of a Serjania marginata leaf extract with antiulcer activity afforded 15 compounds, including the new 3-O-α-L-arabinopyranosyl(1→3)-α-Lrhamnopyranosyl(1→2)[β-D-glucopyranosyl(1→4)]-α-Larabinopyranosyloleanolic acid (1) and 7,5″-anhydroapigenin 8-C-α-(2,6-dideoxy-5-hydroxy-ribo-hexopyranosyl)-4′-O-β-D-glucopyranoside (4). The structures of the new compounds were determined by spectroscopic analysis, including 1D and 2D NMR techniques, mass spectrometry, and chemical methods. Compound 4 is a C-hexopyranosylapigenin with an unusual cyclic ether linkage between C-5″ and C-7 of apigenin. The isolated proanthocyanidins have high antioxidant activities, and these compounds are probably responsible for the gastroprotective effect of the extract.}, publisher = {Journal of Natural Products}, keywords = {serjania marginata}, keywords = {glycosylapigenins}, keywords = {Phytochemistry}, title = {Unusual C,O-Fused Glycosylapigenins from Serjania marginata Leaves}, doi = {10.1021/np500715x}, author = {Heredia-Vieira, Silvia C. and Vilegas, Wagner and Simonet Morales, Ana María and Macías Domínguez, Francisco Antonio}, }