@misc{10498/20374, year = {2016}, month = {12}, url = {http://hdl.handle.net/10498/20374}, abstract = {A methodology to build (E)-β-alkoxy- and (E)-β- aryloxyacrylate moieties from acetate and formate esters promoted by the TiCl4/Et3N system is presented. The reaction is compatible with a broad range of structural skeletons and elapses through an unusual condensation pathway. Taking into account the obtained results, we propose a plausible mechanism involving a bimetallic titanium intermediate for this type of transformation.}, publisher = {ACS Publications}, title = {TiCl4/Et3N‑Mediated Condensation of Acetate and Formate Esters: Direct Access to β‑Alkoxy- and β‑Aryloxyacrylates}, doi = {10.1021/acs.orglett.6b03233}, author = {Álvarez Calero, José María and Jorge Estévez, Zacarías Domingo and Martínez Massanet, Guillermo}, }