@misc{10498/20577, year = {2014}, month = {3}, url = {http://hdl.handle.net/10498/20577}, abstract = {The new mulinane diterpenoids 1 and 2 were isolated from the EtOAc extract of Mulinum crassifolium, while the rearranged mulinane 5, which was isolated for the first time from a natural source, was isolated from Azorella compacta. Compounds 1–2 were prepared by semi-synthesis thorough acetylation of the diterpene 17-acetoxymulinic acid (3). A mechanism of reaction was proposed, while the structures of the new compounds were elucidated on the basis of comprehensive spectroscopic analysis and computational methods.}, publisher = {MDPI}, keywords = {mulinanes}, keywords = {azorellanes}, keywords = {new diterpenoids}, keywords = {Chilean native plants}, keywords = {semisynthesis}, title = {Further Mulinane and Azorellane Diterpenoids Isolated from Mulinum crassifolium and Azorella compacta}, doi = {10.3390/molecules19043898}, author = {Bórquez, Jorge and Ardiles, Alejandro and Loyola, Luis Alberto and Peña-Rodriguez, Luis Manuel and Molina-Salinas, Gloria María and Vallejos, Javier and González Collado, Isidro and J. Simirgiotis, Mario}, }