@misc{10498/20593,
year = {2016},
url = {http://hdl.handle.net/10498/20593},
abstract = {The reaction of geraniol with different lithium carbenoids generated from n-BuLi and the corresponding dihaloalkane has been evaluated. The reaction occurs in a chemo and stereoselective manner, which is consistent with a directing effect from the oxygen of the allylic moiety. Furthermore, a set of polyenes containing allylic hydroxyl or ether groups were chemoselectively and stereoselectively converted into the corresponding gem-dimethylcyclopropanes in one single step in moderate to good yields mediated by a lithium carbenoid generated in situ by the reaction of n-BuLi and 2,2-dibromopropane.},
publisher = {The Royal Society of Chemistry},
title = {Chemoselective and stereoselective lithium carbenoid mediated cyclopropanation of acyclic allylic alcohols},
doi = {10.1039/c5ob02617b},
author = {Durán Peña, María Jesús and Flores-Giubi, M. E. and Botubol Ares, José Manuel and M. Harwood, L. and González Collado, Isidro and Macías Sánchez, Antonio José and Hernández Galán, Rosario},
}