@misc{10498/21336,
year = {2014},
url = {http://hdl.handle.net/10498/21336},
abstract = {Multiple metal-bound oligomers in the dehydropolymerisation of H3B$NH3 have been observed by electrospray-ionisation mass spectrometry and NMR spectroscopy using the catalytic metal fragment {Ir(PCy3)2(H)2}+. A computational study suggests that sterics dictate whether multiple dehydrogenation/ B–N coupling of amine-boranes H3B$NRR'H (R, R0 ¼ Me or H) is observed, and also demonstrates the experimentally observed requirement for additional amine-borane to promote dehydrocoupling.},
publisher = {ROYAL SOC CHEMISTRY},
title = {Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B$NH3 as probed by experiment and computation},
doi = {10.1039/c4sc00735b},
author = {Kumar, Amit and C. Johnson, Heather and N. Hooper, Thomas and S. Weller, Andrew and García Algarra, Andrés and A. Macgregor, Stuart},
}