@misc{10498/26919,
year = {2021},
url = {http://hdl.handle.net/10498/26919},
abstract = {A copper-iron mixed oxide was deposited by the washcoating procedure over cordierite honeycomb monoliths for its use as a heterogeneous catalyst in organic synthesis processes. In particular, the prepared catalyst, characterized by techniques such as X-ray fluorescence, X-ray diffraction, SEM-EDS, laser granulometry, adherence tests, Temperature-Programmed Oxidation and Temperature-Programmed Reduction, showed an excellent yield and stability in the selective production of the allylic ester derived from the Kharasch-Sosnovsky oxidation of cyclohexene with benzoic acid. The use of a structured catalyst here proposed opens up an interesting alternative to homogeneous catalysis in the field of synthetic chemistry. © 2021 The Authors},
organization = {The authors thank the Ministry of Economy and Competitiveness of Spain (Projects MAT2017-85-719-R , and AGL2017-88083-R ), the Junta de Andalucía ( FQM-110 and FQM-169 groups), and the Institute of Electron Microscopy and Materials (IMEYMAT) of Cadiz University (UCA) (Projects HOMOGREEN and NUPRECAT) for their financial support. They also acknowledge the SC-ICYT of the UCA for using its XRD NMR, and electron microscopy division facilities.},
publisher = {ELSEVIER},
keywords = {Allylic oxidation},
keywords = {Copper-iron mixed oxide},
keywords = {Cyclohexene},
keywords = {Honeycomb monoliths},
keywords = {Karasch-Sosnovsky reaction},
title = {Copper-iron mixed oxide supported onto cordierite honeycomb as a heterogeneous catalyst in the Kharasch-Sosnovsky oxidation of cyclohexene},
doi = {10.1016/j.cattod.2021.10.020},
author = {Yeste Siguenza, María del Pilar and Fellak, M. Amine and Vidal Muñoz, Hilario and Guerra Martínez, Francisco Miguel and Moreno Dorado, Francisco Javier and Gatica Casas, José Manuel},
}