@misc{10498/26986, year = {2022}, month = {3}, url = {http://hdl.handle.net/10498/26986}, abstract = {A series of novel nanocomposites containing graphene oxide (GO) suitable for stereolithography is presented. Different loads of GO are tested, identifying that these materials can be printed with concentrations up to 2.5 wt% GO, presenting improved mechanical properties for concentrations below 1.0 wt% GO. In this range, the nanocomposites exhibit higher strength and toughness when compared to the pristine resin. Microscopic analyses of the material demonstrate that this can be correlated with the good compatibility of GO with the resin, which favors its homogeneous dispersion in the form of flexible nanoplates. After manufacturing, the availability of GO to participate in surface modification reactions with chitosan (CHI) and an alkaline phosphatase (ALP) is evaluated. CHI and ALP are well-known to act as biological cues in biorecognition processes, evidencing that these nanocomposites are suitable as platforms for selective immobilization of functional biomolecules.}, organization = {This work was funded by the Ministry of Science, Innovation and Universities (TEC2017-86102-C2-2-R), the 2014-2020 ERDF Operational Programme and the Department of Economy, Knowledge, Business and University of the Regional Government of Andalusia (FEDER-UCA18-106586). Co-funding from UE and the research group INNANOMAT (ref. TEP-946) is also acknowledged. A.S.d.L. and M.d.l.M. acknowledge Ministry of Science, Innovation and Universities for their Juan de la Cierva Incorporacion postdoctoral fellowships (IJC2019-041128-I, IJCI-2017-31507). SEM and TEM measurements were carried out at the DME-SC-ICyT-ELECMI-UCA.}, publisher = {WILEY}, keywords = {functional materials}, keywords = {graphene oxidenano}, keywords = {composites}, keywords = {stereolithography}, keywords = {surface modification}, title = {Printable Graphene Oxide Nanocomposites as Versatile Platforms for Immobilization of Functional Biomolecules}, doi = {10.1002/MAME.202100784}, author = {Sanz de León, Alberto and Mata Fernández, María de la and Delgado González, Francisco Javier and Molina Rubio, Sergio Ignacio}, }