@misc{10498/30244, year = {2018}, url = {http://hdl.handle.net/10498/30244}, abstract = {A thorough study of the fermentation broth of three strains of Botrytis cinerea which were grown on a modified Czapek-Dox medium supplemented with 5 ppm copper sulphate, yielded five undescribed metabolites. These metabolites possessed a sesquiterpenoid (+)-4-epi-eremophil-9-ene carbon skeleton which was enantiomeric to that of the phytoalexin, capsidiol. The isolation of these metabolites when the fungus was stressed, suggests that they may be potential effectors used by B. cinerea to circumvent plant chemical defences against phytopatho genic fungi. The biosynthesis of these compounds has been studied using 2 H and 13C labelled acetate}, publisher = {Elsevier}, keywords = {Botrytis cinerea}, keywords = {Sclerotiniaceae}, keywords = {Biosynthesis}, keywords = {Cryptic metabolites}, keywords = {Eremophilenols}, title = {Structural and biosynthetic studies on eremophilenols related to the phytoalexin capsidiol, produced by Botrytis cinerea}, doi = {10.1016/j.phytochem.2018.06.010}, author = {Moraga, Javier and Suárez Cáceres, Ivonne Rocío and Silva Lima, Gesiane de and Conti, Raphael and Pinedo Rivilla, Cristina and Moraga Galindo, Javier and Barúa, Javier E. and Oliveira, Ana Ligia de and Aleu Casatejada, Josefina and Durán Patrón, Rosa María and Macías Sánchez, Antonio José and Hanson, J. R. and Tallarico Pupo, Monica and Hernández Galán, Rosario and González Collado, Isidro}, }