@misc{10498/30399, year = {2017}, url = {http://hdl.handle.net/10498/30399}, abstract = {novel diterpenoid, gaditanone (2), which possesses an unprecedented 5/6/4/6-fused gaditanane tetracyclic ring skeleton, and a new jatrophane (1) were isolated from the aerial parts of Euphorbia gaditana. The chemical structures and absolute configurations were determined by extensive spectroscopic NMR studies and ECD data analysis. A proposed biosynthetic pathway is presented for compound 2.}, publisher = {AMER CHEMICAL SOC}, keywords = {euphorbia}, keywords = {gaditanone skeleton}, keywords = {natural products}, title = {Gaditanone, a Diterpenoid Based on an Unprecedented Carbon Skeleton Isolated from Euphorbia gaditana}, doi = {10.1021/ACS.JNATPROD.7B00332}, author = {Flores Giubi, Eugenia and Durán Peña, María Jesús and Botubol Ares, José Manuel and Escobar Montaño, Felipe and Zorrilla Cuenca, David and Macías Sánchez, Antonio José and Hernández Galán, Rosario}, }