@misc{10498/30957,
year = {2021},
url = {http://hdl.handle.net/10498/30957},
abstract = {A general and efficient method for the deconjugative
α-alkylation of α,β-unsaturated aldehydes promoted by a
synergistic effect between tBuOK and NaH, which considerably
increases the reaction rate under mild conditions, is reported. The
β,γ-unsaturated aldehyde, resulting from the α-alkylation, is
transformed in high yield into the corresponding allyl acetate via
a lead(IV) acetate-mediated oxidative fragmentation. This strategy
could be used for the construction of the carbon skeleton of a wide
variety of alkyl or arylterpenoids.},
publisher = {AMER CHEMICAL SOC},
title = {Deconjugative α-alkylation of cyclohexenecarboxaldehydes: An access to diverse terpenoids},
doi = {10.1021/ACS.JOC.1C00560},
author = {Chahboun, Rachid and Botubol Ares, José Manuel and Durán Peña, María Jesús and Jiménez, Fermín and Álvarez Manzaneda, Ramón and Álvarez Manzaneda, Enrique},
}