@misc{10498/33898, year = {2017}, url = {http://hdl.handle.net/10498/33898}, abstract = {Colloidal nanorods with axial Si and Ge heterojunction segments were produced by solution-liquid-solid (SLS) growth using Sn as a seed metal and trisilane and diphenylgermane as Si and Ge reactants. The low solubility of Si and Ge in Sn helps to generate abrupt Si-Ge heterojunction interfaces. To control the composition of the nanorods, it was also necessary to limit an undesired side reaction between the Ge reaction byproduct tetraphenylgermane and trisilane. High-resolution transmission electron microscopy reveals that the Si-Ge interfaces are epitaxial, which gives rise to a significant amount of bond strain resulting in interfacial misfit dislocations that nucleate stacking faults in the nanorods.}, publisher = {American Chemical Society}, title = {Colloidal Silicon-Germanium Nanorod Heterostructures}, doi = {10.1021/ACS.CHEMMATER.7B03868}, author = {Lu, Xiaotang and Mata Fernández, María de la and Arbiol, Jordi and Korgel, Brian A.}, }