@misc{10498/36481, year = {2017}, url = {http://hdl.handle.net/10498/36481}, abstract = {A novel methodology for the epoxidation of a broad range of primary, secondary, and tertiary allylic alcohols is described using tert-butyl hydroperoxide as oxidant and Ti(III) species generated by reduction of Ti(IV) complexes, with manganese (0) in 1,4-dioxane under mild reaction conditions. The reaction proceeded with wide substrate scope and high chemo- and diastereoselectivity. A mechanistic pathway for the reaction is also discussed.}, publisher = {American Chemical Society}, title = {Mild Epoxidation of Allylic Alcohols Catalyzed by Titanium(III) Complexes: Selectivity and Mechanism}, doi = {10.1021/ACSOMEGA.7B00386}, author = {Botubol Ares, José Manuel and Hanson, James R. and Hernández Galán, Rosario and González Collado, Isidro}, }