@misc{10498/39558,
year = {2026},
month = {10},
url = {http://hdl.handle.net/10498/39558},
abstract = {The Ruthenium(II) phenylvinylidene complex [RuCp(=C=CHPh)(mPTA)(PPh 3 )](CF 3 SO 3 ) 2 (2) has been synthesized and characterized by NMR, IR and elemental analysis and its structure by single crystal X-ray diffraction (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane). The chemical reactivity of this complex against water, acid medium, O 2 , CO, isopropylamine, cyclohexylamine, 2-aminopyridine, ethanethiol and ethanol was studied. As a result, new amino and thio-carbenes were obtained and characterized. Additionally, complex 2 was evaluated as catalyst for the isomerisation of linear allylic alcohols with different tail lengths.},
publisher = {Elsevier},
keywords = {Ruthenium},
keywords = {Methyl-PTA},
keywords = {Metal vinylidene},
keywords = {Allylic alcohols},
keywords = {Redox isomerization},
keywords = {Water},
title = {Synthesis of the new water soluble vinyl ruthenium complex [RuCp(=C=CPh)(PPh3)(mPTA2](CF3SO3) (mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane): chemical reactivity and catalytic properties for redox isomerization of allylic alcohols},
doi = {10.1016/J.POLY.2025.117850},
author = {Ríos Hierro, Isaac de los and Scalambra, Franco and Jara Pérez, Vicente and Romerosa, Antonio},
}