%0 Journal Article %A Pinedo Rivilla, Cristina %A Moraga Galindo, Javier %A Hernández Galán, Rosario %A Durán Patrón, Rosa María %A González Collado, Isidro %T Botrylactone: new interest in an old moleculedreview of its absolute configuration and related compounds %D 2010 %@ 0040-4020 %U http://hdl.handle.net/10498/17363 %X The absolute configuration of botrylactone, a unique compound with an interesting polyketide lactone skeleton with two oxirane bridges previously isolated from Botrytis cinerea and described as a powerful antibiotic, has been reviewed on the basis of sign of the optical rotation, NOE experiments and NMR method. The isolation of 7-deoxybotrylactone and 5-hydroxy-7-(4-hydroxydec-2(3)-enoyl) botrylactone enables us to characterize an intriguing new family of compounds with this interesting polyketide skeleton. A common biosynthetic origin with botcinin derivatives is proposed. %K Botrylactone %K Absolute configuration %~ Universidad de Cádiz