%0 Journal Article 
%A Bórquez, Jorge
%A Ardiles, Alejandro
%A Loyola, Luis Alberto
%A Peña-Rodriguez, Luis Manuel
%A Molina-Salinas, Gloria María
%A Vallejos, Javier
%A González Collado, Isidro
%A J. Simirgiotis, Mario
%T Further Mulinane and Azorellane Diterpenoids Isolated from Mulinum crassifolium and Azorella compacta
%D 2014
%U http://hdl.handle.net/10498/20577
%X The new mulinane diterpenoids 1 and 2 were isolated from the EtOAc extract of Mulinum crassifolium, while the rearranged mulinane 5, which was isolated for the first time from a natural source, was isolated from Azorella compacta. Compounds 1–2 were prepared by semi-synthesis thorough acetylation of the diterpene 17-acetoxymulinic
acid (3). A mechanism of reaction was proposed, while the structures of the new compounds were elucidated on the basis of comprehensive spectroscopic analysis and computational methods.
%K mulinanes
%K azorellanes
%K new diterpenoids
%K Chilean native plants
%K semisynthesis
%~ Universidad de Cádiz