%0 Journal Article 
%A Flores Giubi, Eugenia
%A Durán Peña, María Jesús
%A Botubol Ares, José Manuel
%A Escobar Montaño, Felipe
%A Zorrilla Cuenca, David
%A Macías Sánchez, Antonio José
%A Hernández Galán, Rosario
%T Gaditanone, a Diterpenoid Based on an Unprecedented Carbon Skeleton Isolated from Euphorbia gaditana
%D 2017
%@ 1520‐6025
%U http://hdl.handle.net/10498/30399
%X novel diterpenoid, gaditanone (2), which possesses an
unprecedented 5/6/4/6-fused gaditanane tetracyclic ring skeleton, and a
new jatrophane (1) were isolated from the aerial parts of Euphorbia
gaditana. The chemical structures and absolute configurations were
determined by extensive spectroscopic NMR studies and ECD data
analysis. A proposed biosynthetic pathway is presented for compound 2.
%K euphorbia
%K gaditanone skeleton
%K natural products
%~ Universidad de Cádiz