%0 Journal Article 
%A Macías Benítez, Pablo
%A Sierra Padilla, Alfonso
%A Jiménez Tenorio, Manuel
%A Moreno Dorado, Francisco Javier
%A Guerra Martínez, Francisco Miguel
%T Copper-Catalyzed Microwave-Expedited Oxyphosphorylation of Alkynes with Diethyl Phosphite and t-Butyl Hydroperoxide Synthesis of Densely Functionalized Phosphonylated Indenones
%D 2021
%@ 1520-6904

%U http://hdl.handle.net/10498/33913
%X Treatment of alkynes with diethyl phosphite and t-butyl hydroperoxide in the presence of [Cu(MeCN)4]BF4 under microwave irradiation produced the oxyphosphorylation of the triple bond, giving rise to the corresponding β-ketophosphonates in moderate-to-good yields. When the triple bond was conjugated to a carbonyl group bearing an aromatic ring, it led to the cyclization of the resulting ketone intermediate, producing eventually different phosphonylated indenones.
%K copper
%K catalyzed
%K microwave
%K expedited
%K oxyphosphorylation
%K alkyne
%K phosphite
%K hydroperoxide
%K phosphonylated
%K indenone
%K preparation
%K derivatization
%~ Universidad de Cádiz