%0 Journal Article 
%A Sokolov, Maxim N.
%A Anyushin, Alexander V.
%A Hernández Molina, Rita
%A Llusar, Rosa
%A García Basallote, Manuel
%T Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization
%D 2017
%@ 1365-3075

%U http://hdl.handle.net/10498/34022
%X This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear
transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo
groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence
of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation
and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination
to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.
%K ICPC-21
%~ Universidad de Cádiz