Preferential oxidation of CO in excess H2 over CuO/CeO2 catalysts:Characterization and performance as a function of the exposed face present in the CeO2 support
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Author/sGamarra, D.; López Cámara, A.; Rasmussen, S.B.; Chinchilla, L.E.; Hungría Hernández, Ana B.; Munuera, G.; Gyorffy, N.; Schay, Z.; Cortés Corberán, V.; Conesa, J.C.; Martínez-Arias, A.
DepartmentCiencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
SourceApplied Catalysis B: Environmental 130– 131 (2013) 224– 238
A series of oxidised copper-cerium nanostructured catalysts prepared by impregnation of copper over ceria supports synthesized by different methods (hydrothermal with varying preparation parameters, microemulsion/precipitation), in order to achieve different specific morphologies (nanocubes, nanorods and nanospheres), have been examined with respect to their catalytic properties for preferential oxidation of CO in excess H2 (CO-PROX). The catalysts have been characterized in detail by XRD, Raman, SBET measurement, HREM, XPS, TPR and EPR, which allows establishing a model of structural characteristics of the catalysts. The characterization results have been correlated with analysis of CO-PROX catalytic properties by means of catalytic activity measurements complemented by operando-DRIFTS. Structural dependence of the CO oxidation reaction on the dispersed copper oxide entities as a function of the exposed face present at the surface of the different ceria supports is revealed. An important overall enhancement of the CO-PROX performance is detected for the sample supported on ceria nanocubes which is proposed to be a consequence of the interaction between copper oxide and (1 0 0) faces of the ceria support.