Asymmetric preparation of antifungal 1-(4 -chlorophenyl)-1-cyclopropyl methanol and 1-(4 -chlorophenyl)-2-phenylethanol. Study of the detoxification mechanism by Botrytis cinerea

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Asymmetric preparation of antifungal 1-(4 -chlorophenyl)-1-cyclopropyl methanol and 1-(4 -chlorophenyl)-2-phenylethanol. Study of the detoxification mechanism by Botrytis cinerea

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Title: Asymmetric preparation of antifungal 1-(4 -chlorophenyl)-1-cyclopropyl methanol and 1-(4 -chlorophenyl)-2-phenylethanol. Study of the detoxification mechanism by Botrytis cinerea
Author: Pinedo Rivilla, Cristina; Aleu Casatejada, Josefina; Hernández Galán, Rosario; González Collado, Isidro; Bustillo Pérez, Antonio
Departments: Química Orgánica
xmlui.dri2xhtml.METS-1.0.item-source: Journal of Molecular Catalysis B: Enzymatic, 2011, vol. 70, pp. 61–66
Abstract: Chiral alcohols are important as bioactive compounds or as precursors to such molecules. On the basis of the different antifungal properties of the enantiopure alcohol derivatives of 4-chlorophenyl cyclopropyl ketone and benzyl 4-chlorophenyl ketone, their enantioselective synthesis by chemical and biocatalytic methods was studied. The detoxification pathways by the phytopathogen fungus Botrytis cinerea are reported.
Subject: Asymmetric preparation ; Botrytis cinerea ; Lipase ; Baker’s yeast ; 1-(4 -Chlorophenyl)-1-cyclopropyl ; 1-(4 -Chlorophenyl)-2-phenylethanol.
Handle: http://hdl.handle.net/10498/17362
Date: 2011-02-24

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