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dc.contributor.authorJiménez-Tenorio, Manuel
dc.contributor.authorPuerta Vizcaino, María del Carmen
dc.contributor.authorValerga Jiménez, Pedro Sixto
dc.contributor.otherCiencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánicaen_US
dc.date.accessioned2018-05-04T10:38:19Z
dc.date.available2018-05-04T10:38:19Z
dc.date.issued2015-02
dc.identifier.urihttp://hdl.handle.net/10498/20447
dc.description.abstractAn atom-economical, more environmentally friendly alternative method of synthesis of the versatile complex [TpRuCl(COD)] (1) (Tp = hydrotris(pyrazol-1-yl)borate; COD = 1,5-cyclooctadiene) has been developed. Instead of starting from [RuHCl(COD)(NH2NMe2)3]+, 1 can be conveniently prepared by reaction of the derivative trans-[RuCl2(COD)(Me2NCH2- CH2NHMe)] (2) with KTp in acetone at 55 °C. Compound 2, which has been structurally characterized by X-ray crystallography, results from an unexpected diamine dealkylation process which takes place in the course of the reaction of [{RuCl2(COD)}n] with tmeda (tmeda = Me2NCH2CH2NMe2) in toluene at 80 °C. This process had been overlooked in the literature, as compound 2 had been misidentified as cis-[RuCl2(COD)(tmeda)], and suggests that amine dealkylation might occur more commonly than previously anticipated.en_US
dc.formatapplication/pdfen_US
dc.language.isoengen_US
dc.publisherACS Publicationsen_US
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.sourceOrganometallics 2015, 34, 1001−1004en_US
dc.titleAtom-Economical Synthesis of the Versatile Ruthenium Precursor [TpRuCl(COD)] (Tp = Hydrotris(pyrazol-1-yl)borate) Discloses a Diamine Ligand Dealkylation Processen_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.identifier.doi10.1021/om501307a


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Attribution-NonCommercial-NoDerivatives 4.0 Internacional
This work is under a Creative Commons License Attribution-NonCommercial-NoDerivatives 4.0 Internacional