Show simple item record

Efficient O-Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoter

dc.contributor.authorDurán Peña, María Jesús 
dc.contributor.authorBotubol Ares, José Manuel 
dc.contributor.authorR. Hanson, James
dc.contributor.authorHernández Galán, Rosario 
dc.contributor.authorGonzález Collado, Isidro 
dc.contributor.otherQuímica Orgánicaen_US
dc.date.accessioned2018-06-06T07:21:37Z
dc.date.available2018-06-06T07:21:37Z
dc.date.issued2016
dc.identifier.urihttp://hdl.handle.net/10498/20594
dc.description.abstractA method has been developed for the conversion of primary, secondary, and tertiary alcohols, and phenol, into the corresponding esters at room temperature. The method uses a titanium(III) species generated from a substoichiometric amount of titanocene dichloride together with manganese(0) as a reductant, as well as methylene diiodide. It involves a transesterification from an ethyl ester, or a reaction with an acyl chloride. A radical mechanism is proposed for these transformations.en_US
dc.formatapplication/pdfen_US
dc.language.isoengen_US
dc.publisherWilleyen_US
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.sourceEuropean Journal of Organic Chemistry. 2016, 3584–3591en_US
dc.subjectEstersen_US
dc.subjectAcylationen_US
dc.subjectRadical reactionsen_US
dc.subjectHalohydrinsen_US
dc.subjectTitaniumen_US
dc.titleEfficient O-Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoteren_US
dc.typejournal articleen_US
dc.rights.accessRightsopen access
dc.identifier.doi10.1002/ejoc.201600496


Files in this item

Name:
2016-Efficient O-Acylation of ...
Size:
1.177Mb
Format:
PDF

This item appears in the following Collection(s)

Show simple item record

Attribution-NonCommercial-NoDerivatives 4.0 Internacional
This work is under a Creative Commons License Attribution-NonCommercial-NoDerivatives 4.0 Internacional