Cu-TiO2/SiO2 photocatalysts for concrete-based building materials: Self-cleaning and air de-pollution performance

Abstract

As a consequence of human activities, today, we are exposed to high pollution levels that cause building materials damage and many diseases. The application of TiO2 as coating on building materials has proven the efficiency of self-cleaning and air de-pollution. However, its performance is limited due to its absorption being exclusively located at UV light. In this study, Cu-TiO2 photocatalysts were integrated into silica sol-gel synthesis to manufacture new long-lasting term coatings with self-cleaning and air purification properties for concretebased building materials. The enhancement of TiO2 photoactivity by incorporating Cu into its network has been clearly demonstrated. The self-cleaning and air de-polluting efficiency were assessed using methylene blue (MB), soot and NO, respectively, indicating that the presence of Cu promotes the TiO2 performance. For low doping levels, by increasing the copper loading, the TiO2 photoactivity increased. The highest efficiency was obtained by the photocatalyst containing 5% copper, which shows maximum destruction of methylene blue and soot of 95% and 50% within 60 min and 168 h of irradiation, respectively. However, higher copper loading led to a decrease in its performance, reaching a total degradation of MB and soot of 90% and 45% after 60 min and 168 h of irradiation, respectively, for the sample containing 15% of copper loading.