RT journal article T1 Botrylactone: new interest in an old moleculedreview of its absolute configuration and related compounds A1 Pinedo Rivilla, Cristina A1 Moraga Galindo, Javier A1 Hernández Galán, Rosario A1 Durán Patrón, Rosa María A1 González Collado, Isidro A2 Química Orgánica K1 Botrylactone K1 Absolute configuration AB The absolute configuration of botrylactone, a unique compound with an interesting polyketide lactoneskeleton with two oxirane bridges previously isolated from Botrytis cinerea and described as a powerfulantibiotic, has been reviewed on the basis of sign of the optical rotation, NOE experiments and NMRmethod. The isolation of 7-deoxybotrylactone and 5-hydroxy-7-(4-hydroxydec-2(3)-enoyl) botrylactoneenables us to characterize an intriguing new family of compounds with this interesting polyketideskeleton. A common biosynthetic origin with botcinin derivatives is proposed. PB Elsevier SN 0040-4020 YR 2010 FD 2010-11-11T00:00:00Z LK http://hdl.handle.net/10498/17363 UL http://hdl.handle.net/10498/17363 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 21-sep-2026