RT journal article
T1 Allylic Oxidation of Alkenes Catalyzed by a Copper−Aluminum Mixed Oxide
A1 García-Cabeza, Ana Leticia
A1 Marín Barrios, Rubén
A1 Moreno Dorado, Francisco Javier
A1 Guerra, Francisco M.
A1 Ortega Agüera, María Jesús
A1 Martínez Massanet, Guillermo
A2 Química Orgánica
K1 allylic oxidation
AB A strategy for the allylic oxidation of cyclic alkenes with a copper−aluminum mixed oxide as catalyst is presented. The reaction involves the treatment of an alkene with a carboxylic acid employing tert-butyl hydroperoxide as the oxidant. In all cases, the corresponding allylic esters are obtained. When L-proline is employed, the allylic alcohol or ketone is obtained. The oxidation of cyclohexene and valencene has been optimized by design of experiments (DoE) statistical methodology.
PB ACS Publications
YR 2014
FD 2014-03
LK http://hdl.handle.net/10498/20368
UL http://hdl.handle.net/10498/20368
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 12-nov-2026