RT journal article
T1 Acyloxylation of 1,4-Dioxanes and 1,4-Dithianes Catalyzed by a Copper−Iron Mixed Oxide
A1 García-Cabeza, Ana Leticia
A1 Marín Barrios, Rubén
A1 Moreno Dorado, Francisco Javier
A1 Vidal Muñoz, Hilario
A1 Guerra, Francisco M.
A1 Ortega Agüera, María Jesús
A1 Gatica Casas, José Manuel
A1 Martínez Massanet, Guillermo
A2 Química Orgánica
K1 Acyloxylation
AB The use of a copper−iron mixed oxide as a heterogeneous catalyst for the efficient synthesis of α-acyloxy-1,4-dioxanes and 1,4-dithianes employing t-butyl peroxyesters is reported. The preparation and characterization of the catalyst are described. The effect of the heteroatoms and a plausible mechanism are discussed. The method is operationally simple and involves low-cost starting materials affording products in good to excellent yields.
PB ACS Publications
YR 2015
FD 2015-06
LK http://hdl.handle.net/10498/20369
UL http://hdl.handle.net/10498/20369
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 06-nov-2026