RT journal article
T1 TiCl4/Et3N‑Mediated Condensation of Acetate and Formate Esters: Direct Access to β‑Alkoxy- and β‑Aryloxyacrylates
A1 Álvarez Calero, José María
A1 Jorge Estévez, Zacarías Domingo
A1 Martínez Massanet, Guillermo
A2 Química Orgánica
AB A methodology to build (E)-β-alkoxy- and (E)-β- aryloxyacrylate moieties from acetate and formate esters promoted by the TiCl4/Et3N system is presented. The reaction is compatible with a broad range of structural skeletons and elapses through an unusual condensation pathway. Taking into account the obtained results, we propose a plausible mechanisminvolving a bimetallic titanium intermediate for this type of transformation.
PB ACS Publications
YR 2016
FD 2016-12
LK http://hdl.handle.net/10498/20374
UL http://hdl.handle.net/10498/20374
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 12-nov-2026