RT info:eu-repo/semantics/article
T1 Further Mulinane and Azorellane Diterpenoids Isolated from Mulinum crassifolium and Azorella compacta
A1 Bórquez, Jorge
A1 Ardiles, Alejandro
A1 Loyola, Luis Alberto
A1 Peña-Rodriguez, Luis Manuel
A1 Molina-Salinas, Gloria María
A1 Vallejos, Javier
A1 González Collado, Isidro
A1 J. Simirgiotis, Mario
A2 Química Orgánica
K1 mulinanes
K1 azorellanes
K1 new diterpenoids
K1 Chilean native plants
K1 semisynthesis
AB The new mulinane diterpenoids 1 and 2 were isolated from the EtOAc extract of Mulinum crassifolium, while the rearranged mulinane 5, which was isolated for the first time from a natural source, was isolated from Azorella compacta. Compounds 1–2 were prepared by semi-synthesis thorough acetylation of the diterpene 17-acetoxymulinicacid (3). A mechanism of reaction was proposed, while the structures of the new compounds were elucidated on the basis of comprehensive spectroscopic analysis and computational methods.
PB MDPI
YR 2014
FD 2014-03
LK http://hdl.handle.net/10498/20577
UL http://hdl.handle.net/10498/20577
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 18-ene-2021