RT journal article
T1 Efficient O-Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoter
A1 Durán Peña, María Jesús
A1 Botubol Ares, José Manuel
A1 R. Hanson, James
A1 Hernández Galán, Rosario
A1 González Collado, Isidro
A2 Química Orgánica
K1 Esters
K1 Acylation
K1 Radical reactions
K1 Halohydrins
K1 Titanium
AB A method has been developed for the conversion of primary, secondary, and tertiary alcohols, and phenol, into thecorresponding esters at room temperature. The method uses a titanium(III) species generated from a substoichiometric amount of titanocene dichloride together with manganese(0) as a reductant, as well as methylene diiodide. It involves a transesterification from an ethyl ester, or a reaction with an acyl chloride. A radical mechanism is proposed for these transformations.
PB Willey
YR 2016
FD 2016
LK http://hdl.handle.net/10498/20594
UL http://hdl.handle.net/10498/20594
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 12-nov-2026