RT journal article
T1 Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B$NH3 as probed by experiment and computation
A1 Kumar, Amit
A1 C. Johnson, Heather
A1 N. Hooper, Thomas
A1 S. Weller, Andrew
A1 García Algarra, Andrés
A1 A. Macgregor, Stuart
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
AB Multiple metal-bound oligomers in the dehydropolymerisation of H3B$NH3 have been observed by electrospray-ionisation mass spectrometry and NMR spectroscopy using the catalytic metal fragment {Ir(PCy3)2(H)2}+. A computational study suggests that sterics dictate whether multiple dehydrogenation/ B–N coupling of amine-boranes H3B$NRR'H (R, R0 ¼ Me or H) is observed, and also demonstrates the experimentally observed requirement for additional amine-borane to promote dehydrocoupling.
PB ROYAL SOC CHEMISTRY
SN 2041-6520
YR 2014
FD 2014
LK http://hdl.handle.net/10498/21336
UL http://hdl.handle.net/10498/21336
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 15-nov-2026