RT journal article
T1 Development of a methodology based on headspace-gas chromatography-ion mobility spectrometry for the rapid detection and determination of patin fish oil adulterated with palm oil
A1 Rosiana Putri, Anggita
A1 Aliaño González, María José
A1 Ferreiro González, Marta
A1 Setyaningsih, Widiastuti
A1 Rohman, Abdul
A1 Riyanto, Sugeng
A1 Palma Lovillo, Miguel
A2 Química Analítica
K1 Patin fish oil
K1 Palm oil
K1 Adulteration
K1 Ion mobility spectrometry
K1 Cheinometrics
K1 Fingerprint
AB The present research intends to develop a new method based on headspace-gas chromatography-ion mobility spectrometry (HS-GC-IMS) for the detection and determination of patin fish oil adulterated with different percentages of palm oil, because it is a cheaper vegetable oil. Five variables that affect headspace generation (incubation time and temperature, amount of sample, injection volume, and pre-heating time) have been optimized by means of a Box Behnken design in combination with Response Surface Methodology. Then, repeatability and intermediate precision have been studied where coefficients of variation lower than 10% were obtained. This new method has been applied to several samples of patin fish oil adulterated with palm oil at 20 different levels (5-50% palm oil content). The results have confirmed the suitability of the HS-GC-IMS for a rapid, easy, and reliable detection and discrimination of adulterated oil samples since a characteristic fingerprint that allows 100% successful discrimination between adulterated and unadulterated patin oil samples was achieved. Finally, a regression model has been developed to determine each sample's adulteration level with an error lower than 10% and a coefficient of determination greater than 0.95. (C) 2020 The Author(s). Published by Elsevier B.V. on behalf of King Saud University.
PB ELSEVIER
SN 1878-5352
YR 2020
FD 2020-10
LK http://hdl.handle.net/10498/23935
UL http://hdl.handle.net/10498/23935
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 05-nov-2026