RT journal article T1 Coastal gradients of small microplastics and associated pollutants influenced by estuarine sources A1 González-Ortegón, Enrique A1 Sendra, Marta A1 Sparaventi, Erica A1 Sanchez Leal, Ricardo F. A1 Ríos Hierro, Isaac de los A1 Baldó, Francisco A1 González Fernández, Daniel A1 Yeste Siguenza, María del Pilar A2 Biología A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica K1 Marine litter K1 Microplastics K1 Estuarine source K1 Oceanographic current K1 Metallic additives K1 Food web AB Small microplastics (SMPs) in the gulf of Cadiz was sampled at 5 m depth by pumping it through the ship's pipe system and filtered through a 45 mu m mesh size net. Our study reveals that higher densities have been found (130 mg.m(-3)) compared to other regions worldwide and these densities decreased from the coastline to the outer stations, showing a general coastal gradient influenced by estuarine outflows. SMPs with a size range between 45 and 193 mu m were predominant and most of them composed by polyethylene and polypropylene. The metals associated with the MPs were mainly Na (21.1%), K (11.3%), Fe (8.5%), Ca (2.1%), Cr (1.8%), Zr (13.3%) and Hf (0.7%). The high proportion of Zr compared to Fe, which is different from what can be found in the environment, PB ELSEVIER SN 0025-326X YR 2022 FD 2022-01 LK http://hdl.handle.net/10498/26471 UL http://hdl.handle.net/10498/26471 LA eng NO Financial support to EGO and the instrument was given by CSIC through Intramural Research program 2018 under grant number 201830I081. MS is grateful to the Spanish Ministry of Science, Innovation and Universities for the Juan de la Cierva (TJFI-2017-32493) contract. DGF was funded by European Union's H2020-MSCA-IF-2018 846843-LitRivus. DS Repositorio Institucional de la Universidad de Cádiz RD 08-nov-2026