RT journal article T1 Photocatalytic TiO2 nanosheets-SiO2 coatings on concrete and limestone: An enhancement of de-polluting and self-cleaning properties by nanoparticle design A1 Luna Aguilera, Manuel Jesús A1 Delgado Jaén, Juan José A1 Romero Ocaña, Ismael A1 Montini, T. A1 Gil Montero, María Luisa Almoraima A1 Martínez López, Francisco Javier A1 Fornasiero, P. A1 Mosquera Díaz, María Jesús A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica A2 Ciencias de la Tierra A2 Química Física K1 TiO2 nanosheets K1 Self-cleaning nanomaterials K1 Photocatalysis photocatalytic K1 NOx abatement K1 Photo-catalytic soot removal AB In this study, we develop TiO2-SiO2 nanocomposites that can be employed as photoactive coatings to createsurfaces with antipollution and self-cleaning properties in urban buildings. In particular, anatase titanium dioxidewith a high percentage of {001} facets, commonly called titania nanosheet (TNS), was used as activephase. This approach allows us to improve the antipollution properties of similar sols based on P25. The obtainedTNS were intensively characterized by UV–Vis diffuse reflectance absorption, X-Ray diffraction and transmissionelectron microscopy to rationalize the sol synthesis and fully understand the photocatalytic performances. Ourresults clearly show that after treating the titania nanosheets with NaOH to remove adsorbed residual fluoridefrom the synthesis, they can be easily dispersed and the photocatalytic activity is dramatically improved. Thismaterial has been shown to effectively reduce concentrations of NOx, soot and organic dyes under simulated sunlight radiation. PB SPRINGER SN 0950-0618 YR 2022 FD 2022 LK http://hdl.handle.net/10498/26688 UL http://hdl.handle.net/10498/26688 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 11-nov-2026