RT journal article
T1 Copper-iron mixed oxide supported onto cordierite honeycomb as a heterogeneous catalyst in the Kharasch-Sosnovsky oxidation of cyclohexene
A1 Yeste Siguenza, María del Pilar
A1 Fellak, M. Amine
A1 Vidal Muñoz, Hilario
A1 Guerra Martínez, Francisco Miguel
A1 Moreno Dorado, Francisco Javier
A1 Gatica Casas, José Manuel
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
A2 Química Orgánica
K1 Allylic oxidation
K1 Copper-iron mixed oxide
K1 Cyclohexene
K1 Honeycomb monoliths
K1 Karasch-Sosnovsky reaction
AB A copper-iron mixed oxide was deposited by the washcoating procedure over cordierite honeycomb monoliths for its use as a heterogeneous catalyst in organic synthesis processes. In particular, the prepared catalyst, characterized by techniques such as X-ray fluorescence, X-ray diffraction, SEM-EDS, laser granulometry, adherence tests, Temperature-Programmed Oxidation and Temperature-Programmed Reduction, showed an excellent yield and stability in the selective production of the allylic ester derived from the Kharasch-Sosnovsky oxidation of cyclohexene with benzoic acid. The use of a structured catalyst here proposed opens up an interesting alternative to homogeneous catalysis in the field of synthetic chemistry. © 2021 The Authors
PB ELSEVIER
SN 0920-5861
YR 2021
FD 2021
LK http://hdl.handle.net/10498/26919
UL http://hdl.handle.net/10498/26919
LA eng
NO The authors thank the Ministry of Economy and Competitiveness of Spain (Projects MAT2017-85-719-R , and AGL2017-88083-R ), the Junta de Andalucía ( FQM-110 and FQM-169 groups), and the Institute of Electron Microscopy and Materials (IMEYMAT) of Cadiz University (UCA) (Projects HOMOGREEN and NUPRECAT) for their financial support. They also acknowledge the SC-ICYT of the UCA for using its XRD NMR, and electron microscopy division facilities.
DS Repositorio Institucional de la Universidad de Cádiz
RD 07-nov-2026