RT journal article T1 Fatty Acid and Tocopherol Composition of Pomace and Seed Oil from Five Grape Varieties Southern Spain A1 Carmona Jiménez, Yolanda A1 Igartuburu Chinchilla, José Manuel A1 Guillén Sánchez, Dominico Antonio A1 García Moreno, María de Valme A2 Química Analítica A2 Química Orgánica K1 winery by-products K1 vegetable oils K1 vitamin E K1 atherogenicity index (AI) K1 thrombogenicity index (TI) K1 ratio between hypo- and hypercholesterolemic fatty acids (H/H) K1 vitamin E activity AB Grape pomace and seeds are important winemaking by-products. Their oils are rich in bioactive compounds such as fatty acids and tocopherols. We have characterized oils from both by-products from five Spanish grape varieties (Palomino Fino, Pedro Ximenez, Muscat of Alexandria, Tempranillo and Tintilla de Rota). A high content of UFAs was found in all the analyzed samples. Grape pomace oils generally had the same oleic acid (PUFA(omega-6)) content as seed oils, and lower PUFA contents; they also had a markedly higher linolenic acid (PUFA(omega-3)) content, improving the PUFA(omega-6)/PUFA(omega-3) ratio. All the oil studied show good indicators of nutritional quality: low values of the atherogenicity (0.112-0.157 for pomace, 0.097-0.112 for seed) and thrombogenicity indices (0.30-0.35 for pomace, 0.28-0.31 for seed) and high values of the relationship between hypo- and hypercholesterolemic fatty acids (6.93-9.45 for pomace, 9.11-10.54 for seed). Three tocopherols were determined: alpha-, gamma- and delta-tocopherol. Pomace oils have higher relative contents of alpha- and delta-tocopherol, whereas seed oils have higher relative contents of gamma-tocopherol. A significantly higher content of total tocopherols has been found in pomace oil; it is higher in the oils from red varieties of pomace (628.2 and 706.6 mg/kg by-product), and in the oils from pomace containing stems (1686.4 mg/kg by-product). All the oils obtained can be considered as a source of vitamin E, and their consumption is beneficial for health. PB MDPI SN 1420-3049 YR 2022 FD 2022-10 LK http://hdl.handle.net/10498/28590 UL http://hdl.handle.net/10498/28590 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 08-nov-2026