RT preprint T1 Pre-composting of municipal solid wastes as enhancer of bio-hydrogen production through dark fermentation process A1 Angeríz Campoy, Ruben A1 Fernández Güelfo, Luis Alberto A1 Álvarez Gallego, Carlos José A1 Romero García, Luis Isidoro A2 Ingeniería Química y Tecnología de Alimentos A2 Tecnologías del Medio Ambiente K1 Bio-hydrogen K1 Co-digestion K1 dark fermentation K1 Organic Fraction of Municipal Solid Waste K1 Food waste K1 Pre-composting AB This study was focused on bio-hydrogen production from thermophilic dry anaerobic acidogenic co-digestion (55 °C and 20 % of total solids) of pre-composted mixtures of organic fraction of municipal solid waste (OFMSW) and food waste (FW). Three different mixture ratios of OFMSW:FW (80:20, 70:30 and 50:50) have been tested. The application of pre-composting improved the hydrolytic and acidogenic phases in the subsequent acidogenic co-digestion, reaching an increase in the bio-hydrogen production in the range of 45.4–46.7 %. In this sense, the best results were obtained for the pretreated mixture with the ratio 70:30, with 42.9 LH2/kg VSadded and 53.9 % of H2 in the biogas. Finally, the kinetic study has corroborated that pre-composting clearly enhances the kinetics of acidogenic fermentation of OFMSW and FW mixtures. In fact, the μmax and YP values for the pretreated mixtures have been increased by a 20 % and 33 % respectively. PB Elservier YR 2022 FD 2022-10-18 LK http://hdl.handle.net/10498/29800 UL http://hdl.handle.net/10498/29800 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 11-nov-2026