RT journal article T1 Structural and biosynthetic studies on eremophilenols related to the phytoalexin capsidiol, produced by Botrytis cinerea A1 Moraga, Javier A1 Suárez Cáceres, Ivonne Rocío A1 Silva Lima, Gesiane de A1 Conti, Raphael A1 Pinedo Rivilla, Cristina A1 Moraga Galindo, Javier A1 Barúa, Javier E. A1 Oliveira, Ana Ligia de A1 Aleu Casatejada, Josefina A1 Durán Patrón, Rosa María A1 Macías Sánchez, Antonio José A1 Hanson, J. R. A1 Tallarico Pupo, Monica A1 Hernández Galán, Rosario A1 González Collado, Isidro A2 BiomedicinaBiotecnología y Salud Pública A2 Química Orgánica K1 Botrytis cinerea K1 Sclerotiniaceae K1 Biosynthesis K1 Cryptic metabolites K1 Eremophilenols AB A thorough study of the fermentation broth of three strains of Botrytis cinerea which were grown on a modifiedCzapek-Dox medium supplemented with 5 ppm copper sulphate, yielded five undescribed metabolites. Thesemetabolites possessed a sesquiterpenoid (+)-4-epi-eremophil-9-ene carbon skeleton which was enantiomeric tothat of the phytoalexin, capsidiol. The isolation of these metabolites when the fungus was stressed, suggests thatthey may be potential effectors used by B. cinerea to circumvent plant chemical defences against phytopatho genic fungi. The biosynthesis of these compounds has been studied using 2H and 13C labelled acetate PB Elsevier SN 0031-9422 YR 2018 FD 2018 LK http://hdl.handle.net/10498/30244 UL http://hdl.handle.net/10498/30244 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 12-nov-2026