RT journal article T1 Combined AOPs for potential wastewater reuse or safe discharge based on multi-barrier treatment (microfiltration-H2O2/UV-catalytic wet peroxide oxidation) A1 Manzano, Manuel A. A1 Rueda-Márquez, Juan José A1 Pintado Herrera, Marina Guadalupe A1 Martín Díaz, María Laura A1 Acevedo Merino, Asunción A1 Manzano, Manuel A. A2 Química Física K1 H2O2 photolysis K1 Accumulated UVC dose K1 Catalytic wet peroxide oxidation K1 4-Chlorophenol K1 Vibrio fischeri K1 Paracentrotus lividus sea-urchin AB The viability of a multi-barrier treatment (MBT) for safe discharge or potential reuse of synthetic industrial wastewater was evaluated in this study. The proposed MBT consists of microfiltration membrane pre-treatment (MF), followed by hydrogen peroxide photolysis (H2O2/UVC) using a medium pressure Hg lamp (MP) and granulate activated carbon (GAC). The synthetic wastewater (SIWW) obtained by addition of different industrial organic pollutant (orange II, phenol, 4-chlorophenol and phenanthrene) to the effluent taken from a municipal wastewater treatment plant was used in this study.At optimal operational conditions complete degradation of added contaminants, about 85% of total mineralization and total disinfection were achieved after MBT treatment. Toxicity tests with Vibrio fischeri and Paracentrotus lividus sea-urchin (fertilization and embryo-larval development assays) were conducted with water after each treatment step and drastic decrease of toxicity was observed after applied process. However, it was demonstrated that after H2O2/UVC step toxicity of water significantly increased and was even higher than that of SIWW. Novel equation for estimation of UVC dose was introduced as one of the most important scaling parameter. The main operational and maintenance cost (O&M) of MBT process was evaluated in this work. Thus, the high quality of the obtained effluent suggests its suitability for water reuse or safe discharge. PB ELSEVIER YR 2015 FD 2015 LK http://hdl.handle.net/10498/30315 UL http://hdl.handle.net/10498/30315 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 10-nov-2026