RT journal article
T1 Gaditanone, a Diterpenoid Based on an Unprecedented Carbon Skeleton Isolated from Euphorbia gaditana
A1 Flores Giubi, Eugenia
A1 Durán Peña, María Jesús
A1 Botubol Ares, José Manuel
A1 Escobar Montaño, Felipe
A1 Zorrilla Cuenca, David
A1 Macías Sánchez, Antonio José
A1 Hernández Galán, Rosario
A2 Química Orgánica
K1 euphorbia
K1 gaditanone skeleton
K1 natural products
AB novel diterpenoid, gaditanone (2), which possesses anunprecedented 5/6/4/6-fused gaditanane tetracyclic ring skeleton, and anew jatrophane (1) were isolated from the aerial parts of Euphorbiagaditana. The chemical structures and absolute configurations weredetermined by extensive spectroscopic NMR studies and ECD dataanalysis. A proposed biosynthetic pathway is presented for compound 2.
PB AMER CHEMICAL SOC
SN 1520‐6025
YR 2017
FD 2017
LK http://hdl.handle.net/10498/30399
UL http://hdl.handle.net/10498/30399
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 07-nov-2026