RT journal article T1 Three-Dimensional Diamond MPCVD Growth over MESA Structures: A Geometric Model for Growth Sector Configuration A1 Lloret Vieira, Fernando Manuel A1 Araújo Gay, Daniel A1 Eon, David A1 Bustarret, Etienne A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica A2 Física Aplicada AB The overgrowth of {100}-oriented patterned diamond substrates by microwave plasma enhanced chemical vapor deposition was studied by transmission electron microscopy through a stratigraphic approach. A sector-like growth behavior is evidenced, resulting from a competition between slowly growing facets at protruding (top) corners and edges against quickly growing facets at recessing (bottom) corners. Depending on the pattern orientation and height, under some particular experimental conditions, it is possible to predict the sequence of growth sectors, and thus to choose the crystallographic orientation of the overgrown surface, by stopping the growth at the right stage. A simple two-dimensional model is provided, allowing the fabrication of structures adapted to the requirements of specific electronic devices. YR 2018 FD 2018 LK http://hdl.handle.net/10498/30535 UL http://hdl.handle.net/10498/30535 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 13-nov-2026