RT journal article T1 Bismuth incorporation and the role of ordering in GaAsBi/GaAs structures A1 Fernández de los Reyes, Daniel A1 Bastiman, Faebian A1 Hunter, Chris J. A1 Sales Lérida, David A1 Sánchez, Ana M. A1 John P.R., David A1 González Robledo, David A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica K1 Bi composition K1 GaAsBi/GaAs epilayers K1 Molecular beam epitaxy AB The structure and composition of single GaAsBi/GaAs epilayers grown by molecular beam epitaxy were investigated by optical and transmission electron microscopy techniques. Firstly, the GaAsBi layers exhibit two distinct regions and a varying Bi composition profile in the growth direction. In the lower (25 nm) region, the Bi content decays exponentially from an initial maximum value, while the upper region comprises an almost constant Bi content until the end of the layer. Secondly, despite the relatively low Bi content, CuPtB-type ordering was observed both in electron diffraction patterns and in fast Fourier transform reconstructions from high-resolution transmission electron microscopy images. The estimation of the long-range ordering parameter and the development of ordering maps by using geometrical phase algorithms indicate a direct connection between the solubility of Bi and the amount of ordering. The occurrence of both phase separation and atomic ordering has a significant effect on the optical properties of these layers. © 2014 Reyes et al.; licensee Springer. PB SPRINGER SN 19317573 YR 2014 FD 2014 LK http://hdl.handle.net/10498/30805 UL http://hdl.handle.net/10498/30805 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 07-nov-2026