RT journal article T1 Modelling of bismuth segregation in InAsBi/InAs superlattices: Determination of the exchange energies A1 Flores Gallegos, Sara A1 Fernández de los Reyes, Daniel A1 Braza Blanco, María Verónica A1 Richards, R. D. A1 Bastiman, F. A1 Ben Fernández, Teresa A1 Ruiz Martín, Nazaret A1 David, John P. R. A1 González Robledo, David A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica K1 Bismuthide K1 Exchange energies K1 InAsBi K1 Segregation AB InAsBi dilute alloys are potential new candidates for the improvement of infrared optoelectronic devices such as photodetectors or lasers. In this work, InAsBi/InAs superlattices (SLs)with Bi contents ranging between 1 and 3% were grown by molecular beam epitaxy with different Bi fluxes and growth temperatures to analyze Bi segregation by cross sectional transmission electron microscopy techniques. Bi segregation profiles have been described layer-by-layer using a three-layer fluid exchange mechanism, extracting the values of the As/Bi exchange energies (E1, 1.26 ± 0.01 eV and E2, 1.36 ± 0.02 eV). A relationship to calculate the activation energies for exchange from the binding energies in III–V alloys is proposed, which would allow predicting them for other hitherto unknown compounds. PB Elsevier SN 01694332 YR 2019 FD 2019 LK http://hdl.handle.net/10498/30881 UL http://hdl.handle.net/10498/30881 LA eng DS Repositorio Institucional de la Universidad de Cádiz RD 22-sep-2026