RT journal article
T1 Effect of fast heating and cooling in the hydrothermal synthesis on LiFePO4 microparticles
A1 Ruiz Jorge, Francisco
A1 Benítez, A.
A1 Fernández García, Susana
A1 Sánchez Oneto, Jezabel
A1 Portela Miguélez, Juan Ramón
A2 Ingeniería Química y Tecnología de Alimentos
K1 LiFePO4
K1 Hydrothermal systhesis
K1 Lithium-ion batteries
AB Hydrothermal synthesis is a chemical process that has gained much interest in recent years, especially for the synthesis of LiFePO4 since it is a method that requires a relatively low temperature, short reaction time, and it is reproducible. In this work, LiFePO4 microparticles have been synthesized by means of a fast heating system (sand bath) under hydrothermal conditions. The experiments have been carried out under two different heating rates (86 °C/min and 5.26 °C/min), two different residence times (5 and 30 min), and two different cooling rates (−455 °C/min and −8 °C/min). The effects that these three parameters had on the synthesized particles were verified using several techniques such as X-ray diffraction and scanning electron microscopy. It was observed that the heating rate had a great influence on the purity, crystallization, and morphology of the synthesized LiFePO4 particles. In addition, the high influence of cooling rate on the crystallization and morphology of the particles was also analyzed.
PB ACS Publications
SN 1520-5045
YR 2020
FD 2020-04-21
LK http://hdl.handle.net/10498/30954
UL http://hdl.handle.net/10498/30954
LA eng
NO Ayudas grupos PAIDI Junta de Andalucía
DS Repositorio Institucional de la Universidad de Cádiz
RD 11-nov-2026