RT journal article
T1 Deconjugative α-alkylation of cyclohexenecarboxaldehydes: An access to diverse terpenoids
A1 Chahboun, Rachid
A1 Botubol Ares, José Manuel
A1 Durán Peña, María Jesús
A1 Jiménez, Fermín
A1 Álvarez Manzaneda, Ramón
A1 Álvarez Manzaneda, Enrique
A2 Química Orgánica
AB A general and efficient method for the deconjugativeα-alkylation of α,β-unsaturated aldehydes promoted by asynergistic effect between tBuOK and NaH, which considerablyincreases the reaction rate under mild conditions, is reported. Theβ,γ-unsaturated aldehyde, resulting from the α-alkylation, istransformed in high yield into the corresponding allyl acetate viaa lead(IV) acetate-mediated oxidative fragmentation. This strategycould be used for the construction of the carbon skeleton of a widevariety of alkyl or arylterpenoids.
PB AMER CHEMICAL SOC
SN 1520-6904
YR 2021
FD 2021
LK http://hdl.handle.net/10498/30957
UL http://hdl.handle.net/10498/30957
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 06-nov-2026