RT journal article
T1 Ultrapure Green High Photoluminescence Quantum Yield from FAPbBr3 Nanocrystals Embedded in Transparent Porous Films
A1 Romero-Pérez, C.
A1 Fernández Delgado, Natalia
A1 Herrera Collado, Miriam
A1 Calvo, M.E.
A1 Míguez, H.
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
AB Achieving highly transparent and emissive films based on perovskite quantum dots (PQDs) is a challenging task since their photoluminescence quantum yield (PLQY) typically drops abruptly when they are used as building blocks to make a solid. In this work, we obtain highly transparent films containing FAPbBr3 quantum dots that display a narrow green emission (λ = 530 nm, full width at half-maximum (FWHM) = 23 nm) with a PLQY as high as 86%. The method employed makes use of porous matrices that act as arrays of nanoreactors to synthesize the targeted quantum dots within their void space, providing both a means to keep them dispersed and a protective environment. Further infiltration with poly(methyl methacrylate) (PMMA) increases the mechanical and chemical stability of the ensemble and serves to passivate surface defects, boosting the emission of the embedded PQD and significantly reducing the width of the emission peak, which fulfills the requirements established by the Commission Internationale de l’Éclairage (CIE) to be considered an ultrapure green emitter. The versatility of this approach is demonstrated by fabricating a color-converting layer that can be easily transferred onto a light-emitting device surface to modify the spectral properties of the outgoing radiation.
PB American Chemical Society
SN 1520-5002, 0897-4756
YR 2023
FD 2023
LK http://hdl.handle.net/10498/31412
UL http://hdl.handle.net/10498/31412
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 13-nov-2026