RT journal article
T1 Evidence for Ruthenium(II) Peralkene Complexes as Catalytic Species during the Isomerization of Terminal Alkenes in Solution
A1 Sanz-Navarro, Sergio
A1 Ballesteros-Soberanas, Jordi
A1 Martínez-Castelló, Aarón
A1 Doménech-Carbó, Antonio
A1 Hernández Garrido, Juan Carlos
A1 Cerón-Carrasco, José Pedro
A1 Mon, Marta
A1 Leyva-Pérez, Antonio
A2 Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica
AB The isomerization (chain-walking) reaction of terminal tointernal alkenes is catalyzed by part-per-million amounts of practically any Rusource when the reaction is carried out with a neat terminal alkene. Here, weprovide evidence that the soluble starting Ru sources evolve to catalyticallyactive peralkene Ru(II) species under reaction conditions. These species mayalso explain the isomerization products found during other Ru-catalyzedalkene processes, i.e., alkene metathesis reactions. A Finke−Watzkymechanism for catalyst formation is consistent with the evidence obtained.
PB ACS Publications
SN 1520-510X
YR 2023
FD 2023
LK http://hdl.handle.net/10498/31608
UL http://hdl.handle.net/10498/31608
LA eng
DS Repositorio Institucional de la Universidad de Cádiz
RD 13-nov-2026